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Thursday, January 29, 2015

#205 - What is iEAF?

In Post #194, we asked the question - What is iBOF? In this post we will discuss iEAF.

To begin, it will be helpful to describe EAF. The acronym stands for Electric Arc Furnace and is used to describe a method of steelmaking that heats the charged material using a powerful electric arc originating from large graphite electrodes.

From Wikipedia: 
An electric arc furnace used for steelmaking consists of a refractory-lined vessel, usually water-cooled in larger sizes, covered with a retractable roof, and through which one or more graphite electrodes enter the furnace. The furnace is primarily split into three sections:
  • the shell, which consists of the sidewalls and lower steel "bowl";
  • the hearth, which consists of the refractory that lines the lower bowl;
  • the roof, which may be refractory-lined or water-cooled, and can be shaped as a section of a sphere, or as a frustum (conical section). The roof also supports the refractory delta in its centre, through which one or more graphite electrodes enter.
The hearth may be hemispherical in shape, or in an eccentric bottom tapping furnace, the hearth has the shape of a halved egg. In modern meltshops, the furnace is often raised off the ground floor, so that ladles and slag pots can easily be maneuvered under either end of the furnace. Separate from the furnace structure is the electrode support and electrical system, and the tilting platform on which the furnace rests. Two configurations are possible: the electrode supports and the roof tilt with the furnace, or are fixed to the raised platform.



iEAF stands for “intelligent Electric Arc Furnace” and is a trademark of Tenova Goodfellow Inc. The iEAF system is a progressive, modular technology package designed to provide sustainable long-term cost savings to steelmakers. The system uses dynamic control and holistic optimization of the EAF process.

iEAF® enabling technology can be applied to all variations of the EAF process including: 
  • top charge melting furnaces (bucket and/or shaft) using scrap, DRI and/or pig iron;
  • the Consteel® process (iConsteel®) with or without hot metal;
  • continuous DRI fed furnaces (iDRI®).


While the basic structure remains constant, the automation hardware, software and communication modules can be customized according to the individual customer’s existing automation system and network.

The iEAF technology package is comprised of well-defined modules which each focus on a specific aspect of the EAF process. 
  • MODULE 1 - Dynamic Chemical Energy Control & Optimization (EFSOP)
  • MODULE 2 - Dynamic Melting Control
  • MODULE 3 - Dynamic End-Point Control




While the iEAF® can be easily integrated with any existing automation and process control system, the cornerstone and necessary first step in the iEAF® technology program is EFSOP® off-gas analysis; other off-gas analysis methods which cannot provide complete analysis of CO, CO2, H2 and O2 lack a necessary prerequisite for determining an online Mass & Energy Balance which is critical for efficient energy utilization and effective dynamic control of the melting and refining processes.





MAIN BENEFITS
• Dynamic Control & Optimization of the Melting & Refining Process
• Electrical Energy Savings
• Fuel Savings
• Reduced Power-On Time
• Increased Yield
• Reduced Tap Additions
• Electrode, Delta & Refractory Savings
• Reduced Tap-to-Tap Time
• Reduced Emissions

There are other add-on technologies that are available under the iEAF umbrella. We’ll elaborate on those in a future post.

For more information, contact:

Tenova Goodfellow Inc.
6711 Mississauga Road, Suite 200
Mississauga, ON
L5N 2W3 - Canada
Phone +1 905 567 3030
Fax +1 905 567 3899
goodfellow@ca.tenovagroup.com

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Thursday, January 22, 2015

#204 - Zamboni engine exhaust

Canada’s 2014 gold victory at the IIHF World Juniors was great fun for Canadians especially. But in general, the speed of play and puck handling during the World Junior tournaments is always a marvel to watch.

FRANK GUNN / THE CANADIAN PRESS


And we found this fun pic
for the Habs fans on Pinterest.


Explanations of the physical mechanics of ice skating have evolved over the years. From Wikipedia
A skate can slide over ice because the ice molecules at the surface cannot properly bond with the molecules of the mass of ice beneath and thus are free to move like molecules of liquid water. These molecules remain in a semi-liquid state, providing lubrication. 
It had long been believed that ice is slippery because the pressure of an object in contact with it causes a thin layer to melt. The hypothesis was that the blade of an ice skate, exerting pressure on the ice, melts a thin layer, providing lubrication between the ice and the blade. This explanation, called "pressure melting", originated in the 19th century. This, however, did not account for skating on ice temperatures lower than −3.5 °C, whereas skaters often skate on lower-temperature ice. In the 20th century, an alternative explanation, called "friction heating", was proposed, whereby friction of the material was causing the ice layer melting. However, this theory also failed to explain skating at low temperature. In fact, neither explanation explained why ice is slippery when standing still even at below-zero temperatures.



Professor Gabor Somorjai of Lawrence Berkeley National Laboratory has studied the mechanics of skating and has found that an ice skate blade actually glides on vertically vibrating ice molecules that behave in a ‘liquid-like’ manner without actually melting and turning into liquid.


Many hockey players and coaches agree that good skating is a combination of strength and technique. But smooth skating and puck-handling are also enabled by a device that is usually activated when no skaters are on the ice. A resurfacing machine is used to wash the ice, shave the surface, and leave behind a layer of water that will freeze to form a fresh layer of ice. One of the most well-known examples in North America of an ice resurfacing machine is the Zamboni.

In 1949, Mr. Frank Zamboni developed the world’s first ice resurfacing machine. Based on a Jeep chassis, this machine automatically and quickly provided all of the necessary operations required for pristine skating ice. It also had built-in reservoirs to collect the old shaved ice and distribute the new ice-making water.




Newer Zamboni models are available with electric power supplied by rechargeable batteries. However, many of the Zamboni engines are powered by gas, propane, or CNG (compressed natural gas), similar to fork lift trucks. With an internal combustion engine, there will be an exhaust gas flow. Because these vehicles function indoors in a populated environment, it is important to keep the engines in good repair to minimize impact on indoor air quality.



Nova has various gas analysis capabilities including the gases that typically make up engine exhaust. Our 7460 Series Portable Engine Exhaust Analyzers are available in various combinations including O2, CO, CO2, HC, & NOx. Our customers have used this analyzer on diesel, gasoline, propane, or natural gas powered 2 and 4 cycle engines.

The 7460 Series is a portable analyzer that uses infrared and electrochemical sensors / detectors. Here it is in our on-line catalog.



We aren’t engine mechanics. However, we do build these analyzers to meet Bar 97 and ISO 3930/OIML R99, Class O specifications. Therefore, many mechanics have effectively used this analyzer for reliable engine tuning and emissions reduction. We have noticed that this analyzer is also popular among equipment mechanics who work on forklifts and other non-road vehicles such as Zambonis.

Added March 2013 - We have noticed that our fork-lift customers frequently print on the analyzer cabinet the target gas readings for a properly tuned engine. For example, we have a couple of units in the Nova lab right now being calibrated for one of our customers. They have printed the following target gas readings on the analyzer:

O2: 0.8 % to 2.0 %
CO: 0.1% to 0.8 %
CO2: more than 11.0 %
HC's: less than 200ppm

If you are in the business of tuning engines and require analysis of engine exhaust, ask Mike or Dave for help with the 7460 Series Gas Analyzers.

If you're a Leafs fan, there may not be anything we can do to help you.

1-800-295-3771
sales at nova-gas dot com
websales at nova-gas dot com


Zamboni pics from Zamboni website.

Thursday, January 15, 2015

#203 - Nova Analyzers from the Field – Episode 10 – Fuel Cells and Hydrogen Analysis

Measuring hydrogen (H2) is something we do a lot of here at Nova. We can measure it in a mixed background of other gases, or in a binary mixture of H2 in one other gas such as O2, N2, Ar, etc.

One application that generally requires H2 analysis in a binary mixture with N2 is fuel cell operation and development. We were sent some pics a while back from a fuel cell manufacturer. They use Nova instruments to measure H2.



From Wikipedia, a general description of fuel cell operation is as follows:
Fuel cells come in many varieties; however, they all work in the same general manner. They are made up of three adjacent segments: the anode, the electrolyte, and the cathode. Two chemical reactions occur at the interfaces of the three different segments. The net result of the two reactions is that fuel is consumed, water or carbon dioxide is created, and an electric current is created, which can be used to power electrical devices, normally referred to as the load.



At the anode a catalyst oxidizes the fuel, usually hydrogen, turning the fuel into a positively charged ion and a negatively charged electron. The electrolyte is a substance specifically designed so ions can pass through it, but the electrons cannot. The freed electrons travel through a wire creating the electric current. The ions travel through the electrolyte to the cathode. Once reaching the cathode, the ions are reunited with the electrons and the two react with a third chemical, usually oxygen, to create water or carbon dioxide.
  
The most important design features in a fuel cell are:
  • The electrolyte substance. The electrolyte substance usually defines the type of fuel cell.
  • The fuel that is used. The most common fuel is hydrogen.
  • The anode catalyst breaks down the fuel into electrons and ions. The anode catalyst is usually made up of very fine platinum powder.
  • The cathode catalyst turns the ions into the waste chemicals like water or carbon dioxide. The cathode catalyst is often made up of nickel but it can also be a nanomaterial-based catalyst.

In the specific project from which the field pictures were taken, the requirement was for measurement of 0-100.0 % H2. The sample is typically 70-90% H2 in balance N2, and is obtained at the anode portion of the fuel cell. Measuring the H2 here is useful in evaluating what the cell’s power output will be.

The sample itself is clean and basically dry, with the possibility of occasional moisture in some operation conditions. The gas analyzer has a condensate collection system and a liquid block membrane to avoid water infiltration to the detector. The sample gas is under pressure up to 1.2 barg (17psig). The analyzer has a built-in regulator. The fuel cell manufacturer uses a peristaltic pump to push the sample that is vented out of the analyzer back into the process to maintain the system gas composition.

Connection to the analyzer itself is quite simple, as shown in this picture.



One potential safety concern is related to the possibility of a gas leak occurring inside the analyzer cabinet. We can offer an ex-proof leak detector that is mounted in the cabinet which will de-power the analyzer in the event of a leak. To actively dilute a potential leak, we can also arrange a continuous vent flow through the analyzer using a fan. This is only suitable in clean environments with stable warm temperatures.

On this project, the fuel cell manufacturer and end-user have been very happy with the Nova units. They have since ordered a few spare filters in anticipation of normal maintenance.

For information on these and other gas analyzer systems, give Mike or Dave at Nova a call, or send us an e-mail.

If you have any Nova instruments at your plant or lab and want to share a couple of photos, feel free to send them to us along with a brief explanation of your application.

1-800-295-3771
sales at nova-gas dot com
websales at nova-gas dot com
http://www.nova-gas.com/


*Fuel cell diagrams from Wikipedia, in public domain.
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Friday, January 9, 2015

#202 - GE 7216 V2.2 H2 Analyzer available at Nova

Over the years, we have had many requests for an analyzer system called GE 7216 V2.1 or V2.2. We used to manufacture this product for GE. It was specifically for use as a stator leak detector on large electric generators. In time, some of the components and technologies used in this analyzer were discontinued and subsequently updated.

We have also noticed that the functionality of some of these systems has been impaired by moisture ingress over the years. On most sites, the moisture removal systems prior to the H2 detector have been designed and installed by the original generator provider. If these fail, moisture can enter the H2 detector and ruin it.

Even though the GE 7216 V2 is no longer available to electric power providers, we do have a couple of options to allow you to proceed with a solution.

Replacement detector assembly – If all of the other components on the system are functioning properly, and an updated detector is all that is needed, we may be able to provide a heated box assembly with the updated detector inside. This option is not available in every case, but may be worth inquiring about.



Replacement gas analyzer – The GE 7216 V2 product was in production quite a number of years ago. Many of the installations are getting old or have been contaminated with water, and require replacement instead of repair. The Models 430VN4 and 430QN4 Continuous Hydrogen Monitor are available for this purpose.


The various components are now protected inside a common NEMA 4 wall-mount cabinet. The H2 reading is displayed locally on the analyzer cabinet, and is also sent to an analog 4-20mA output. As an option, we can make this an isolated or non-isolated output. We can also provide a hydrogen alarm with indicator light and relay contact.

The slight difference in model numbers designates the design of moisture removal system. Some installations have a supply in instrument air already connected to the old 7216 module. The new 430VN4 can also utilize this air supply. If there is no instrument air available, the model 430QN4 can be used instead.

If you have a 7216 and are experiencing age- or moisture-related problems, we can undoubtedly assist you. Contact us by e-mail. Be sure to state your 4-digit serial number and full model number.

1-800-295-3771
websales at nova-gas dot com

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Monday, December 29, 2014

#201 - Top 10 Nova Blog Posts from 2014

Probably everyone does a year-end post about what content was most popular on their blog. The areas of interest sometimes indicate an explainable trend, and sometimes they don’t. Nova is a technical company that manufactures analytical instruments. So our audience tends to be of the engineering and analytical types.

Our top 10 posts from 2014 are the following:

1. Post #167 - Using the Energiron Process with SynGas for DRI Production
2. Post #169 - Most Common Connections to Nova Analyzers (electrical & tubing)
3. Post #175 - Tenova Factories
4. Post #171 - New TGI White paper - Real-Time Water Detection in EAF Steelmaking
5. Post #173 - Nova tech climbs Mount Kilimanjaro
6. Post #168 - Nova Analyzers from the Field – Episode 4
7. Post #172 - Ash Classification Technology for Coal-fired Power Plants
8. Post #174 - Nova Analyzers from the Field – Episode 5
9. Post #178 - Nova Analyzers from the Field – Episode 6
10. Post #182 - Oil & Gas Spills Increase in 2013

For the most part, these posts from 2014 have simply accumulated higher popularity because they are from the first half of the year and are obviously older than any recent posts.

In terms of persistent interest, our ‘Analyzers from the Field’ posts seem to do well. People are always interested in reading about something ‘real world’. Frequently, these instruments have been in service for a number of years and have some kind of back-story that may be instructive.

Regarding Post #173 mentioned above, in May of 2014, one of our tech staff ventured to Africa to climb Mount Kilimanjaro. Lots of readers from inside and outside the Tenova Group were interested to hear the story and see the pictures. We still have tons of pics besides what we posted. We'll share a few more soon. 

Our all-time #1 post continues to be Post #70 - "Post #5 is our most popular blog post (Syngas and Gasification)". This one started out as a commentary on another popular post and then itself became most widely read. It indicates the continued interest in measuring the gas compositions produced by gasifiers.

Looking forward to 2015!

For information on these and other gas analyzer systems, give Mike or Dave at Nova a call, or send us an e-mail.

If you have any Nova instruments at your plant or lab and want to share a couple of photos, feel free to send them to us along with a brief explanation of your application.

1-800-295-3771
sales at nova-gas dot com
websales at nova-gas dot com
http://www.nova-gas.com/

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Thursday, December 18, 2014

#200 - Nova Analyzers from the Field - Episode 9 (Studies of CO2 Absorption / Desorption by Amine Solutions)

We were recently sent a published paper containing a brief mention of a Nova analyzer. The paper itself is about the kinetics of CO2 absorption in various aqueous amine solutions. We have periodically addressed this type of application over the years. As carbon dioxide (CO2) becomes more prominently connected with concerns about greenhouse gases, we expect to see more of it in the future also.

From the Introduction of the paper: 
“The separation of acid gas impurities such as carbon dioxide (CO2) and hydrogen sulfide (H2S) from gas mixtures is an important operation in natural gas processing, petroleum refining, coal gasification and ammonia manufacturing industries. Since CO2 is widely regarded as a major greenhouse gas, potentially contributing to global warming, recently, there has also been considerable interest in developing technologies for capturing and sequestering large quantities of CO2 produced from industrial sources such as fossil-fuel electric power generation facilities. Various technologies have been developed for CO2 and H2S removal from gas streams. These include absorption by chemical and physical solvents, cryogenic separation and membrane separation. Among these methods, gas absorption by chemical solvents such as aqueous solutions of alkanolamines is one of the most popular and effective methods.”

Even though this area of study has been active and applied in industry for over 50years, the authors note that complete investigations with mathematical models for absorption and desorption have been lacking. The authors then present a more unified approach in an effort to allow more standardized evaluations of this application across different reactions.

In this study, a novel design of laboratory contactor apparatus was used for interfacial contact between the amine and CO2. This apparatus allows for accurate and easier evaluation of physical mass transfer between the reactants. A diagram of the apparatus as presented in the paper is shown below.



The complete experimental setup from the paper is shown below:



After the dryer and just prior to the fume hood, the CO2 analyzer is shown in the above setup diagram. In this particular study the authors cite the Nova Model 300 infrared analyzer. In our experience, we have supplied a couple of different instruments for this type of application.
-          Model 302A – CO2 analysis by infrared detector
-          Model 336BT – CO2 analysis by thermal-conductivity (not shown in on-line catalog)

In one application in 2013, we supplied multiple units of Model 336BT in two ranges:
-          0-25.0 % CO2 in Air
-          0-100.0 % CO2 in Air

This application was for a large educational training assembly that involved the same absorption reactions between amine & CO2 mentioned above. The different instrument ranges corresponded to different points in the process before & after CO2 absorption. Purchasing separate instruments allowed simultaneous measurement of each point over a specific period of time.

In most cases, these studies are performed using portable instruments that provide accurate analysis on a temporary / intermittent basis. A wall-mounted version of this instrumentation can also be produced. For study apparatuses that are large enough to be permanently installed, a wall-mount analyzer in its own steel cabinet may be desired.



The study mentioned above is actually described in a two part paper as follows:

Part 1
Kinetics of carbon dioxide absorption and desorption in aqueous
alkanolamine solutions using a novel hemispherical contactor—I:
Experimental apparatus and mathematical modeling.

Part 2
Kinetics of carbon dioxide absorption and desorption in aqueous alkanolamine solutions using a novel hemispherical contactor—II: Experimental results and parameter estimation

Authors:
Aqil Jamal
Axel Meisen
C. Jim Lim
Department of Chemical and Biological Engineering,
The University of British Columbia
Vancouver, BC Canada V6T 1Z3


For information on these and other gas analyzer systems, give Mike or Dave at Nova a call, or send us an e-mail.
1-800-295-3771
sales at nova-gas dot com
websales at nova-gas dot com

Hey, this is Post #200 in our blog. Still haven’t run out of things to say!


Author: Aqil Jamal, Axel Meisen and C. Jim Lim
Publication: Chemical Engineering Science
Publisher: Elsevier
Date: October 2006
Copyright © 2006 Elsevier Ltd.
All rights reserved.
* Experiment diagrams and information property of authors

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Friday, December 12, 2014

#199 - Why Buy 970?

The most popular post on this blog is #70, which is ironically entitled “Post #5 is Our Most Popular Blog Post”. Post #70 was intended to highlight the previous successful post #5 that discussed the growing interest in our 970 Series analyzers for syngas applications.

These posts are probably so popular because there is much world-wide interest in gasification as an energy source. These posts contain specific information and pictures about gas analyzers that can successfully measure O2 / CO / CO2 / CH4 / H2 in produced syngas.

We are often asked questions about the price and configuration of the 970 Series. We do have instruments in our product line that are much smaller and simpler (as pictured below). There are other analyzer manufacturers in the marketplace that also have multi-gas capability like Nova, but who are possibly lower-cost. For a gasification application, is it simply a matter of obtaining an analyzer that will measure the gases of interest?




Not always. Gas analysis is usually only the second half of the whole task. The first half involves extracting the sample, filtering it, and drying it. Doing this properly in a syngas application is important.

There is an old saying about comparing ‘apples to apples’. When we are asked to compare the 970 to another analyzer that resembles the picture above, the first thing that we notice is that all of the sample extraction and conditioning components are missing. Unless the end-user is absolutely confident that the produced gas is clean and dry, this style of instrument will not function properly for very long. Trust us - we have learned that lesson the hard way in the past.

The Nova 970 Series Syngas and Gasification Analyzers are analytical instruments that are industrially hardened but user-friendly.
  • High temp probe & heated filter at extraction point.
  • Choice of compression or thermoelectric style moisture removal.
  • Weather-proof cabinet with climate control.
  • Stainless steel tubing and industrial components.
  • Temperature-controlled detectors for O2 / CO / CO2 / CH4 / H2
  • Accurate H2 measurement in varying background gases.
  • High measurement ranges available; up to 100%.
  • Built-in ‘Smart Control’ analyzer functions




Here is some more information plus a link to the 970 section of the catalog. 

For information on these and other gas analyzer systems, give Mike or Dave at Nova a call, or send us an e-mail.
1-800-295-3771
sales at nova-gas dot com
websales at nova-gas dot com
http://www.nova-gas.com/